A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. Weld cracking several types of discontinuities may occur in welds or. Effect of temperature in hydrogen embrittlement in stainless steel, and fusion in inox steel. Hydrogeninduced cracking, or hydrogen embrittlement, is a chemical phenomenon that causes metal alloys to fracture due to a buildup of hydrogen molecules within the crystal lattice structure. On the stress corrosion cracking and hydrogen embrittlement. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants.
Hydrogen damage figure 1 is encountered in many steel processes, such as pickling, electroplating and welding. Effects of hydrogen on the flow stress of type 316 stainless steel are discussed in detail in refs. The measured hydrogen content in parts of the material exceeded 40 ppm, more than an order of magnitude higher than what is normally expected in super duplex stainless steels. The effects of hydrogen on the phase transition and the relative role of the metallurgical variables is discussed. Low temperature has been shown to have a significant effect on the hydrogenassisted fracture of type 316 stainless steel. Hydrogen embrittlement of steel industrial metallurgists. Woollin p and gregori a, avoiding hydrogen embrittlement stress cracking of ferritic austenitic stainless steels under cathodic protection, proc conf omae 2004, paper 51203. Susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. Effect of microstructure on hydrogeninduced cracking of. If hydrogen embrittlement takes place at room temperature, the hydrogen atoms are then absorbed into the lattice of stainless steel. Because this cracking occurs after the steel has cooled below approximately 400f, it can be called cold cracking, and because it is associated with hydrogen, it is also called hydrogen assisted cracking. Nov 21, 2018 an illustration of cracking associated with the hydrogen embrittlement of austenitic stainless steel that is pulled in tension. Hydrogen induced stress cracking of duplex stainless steel.
The methane gas is not mobile and collects in small voids along the grain boundaries where it. The results showed that the failure developed from a combination of factors, typical for hydrogeninduced stress cracking. Hydrogen embrittlement tends to occur at stressconcentrated regions. The results showed that the failure developed from a combination of factors, typical for hydrogen induced stress cracking. Delayed cracking also known as hydrogen induced cracking or cold cracking, occurs when the following three factors are present at the same time. The stress thus induced causes cracking, and the path is called transgranular. Hydrogen enhances crack propagation rates hydrogen reduces the stackingfault energy of 310s stainless steel by 20%. Cathodic hydrogen absorption cha is a subset of scc. Room temperature cathodic charging of unstressed specimens produces intergranular and secondary.
Hydrogeninduced cracking hic is the stepwise internal cracks that connect adjacent hydrogen blisters on different planes in the metal, or to the metal surface. Hydrogen induced cracking hic is most commonly encountered in steels but other metals are susceptible, as shown in table 33. These atoms are then defused through the grains, and create lattice defects. Numerical simulation on effect of microstructure on. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from excessive internal hydrogen pressure. Hic steel hydrogen induced cracking supplier company. Hydrogen cracking in metastable austenitic stainless. Another possible mechanism of hydrogen embrittlement is the pressure build up occurs from within the metal due to the continuous diffusion of hydrogen atom into the stainless steel. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering. The hydrogen is first produced as hydrogen atoms h which normally combine rapidly to form hydrogen molecules h 2. Cracks were observed at boundaries of ferrite and austenite phases. Hydrogeninduced cracking of weld metal of austenitic stainless steels.
The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stressoriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after. Hydrogeninduced cracking hic in steel is a risk problem when steels are. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Hydrogen embrittlement of stainless steel hydrogen diffuses along the grain boundaries and combines with the carbon, which is alloyed with the iron, to form methane gas. The microstructure of the steel also exhibited nitride precipitates within the ferrite grains. A small number of duplex and superduplex stainless steel components have failed in subsea service due to hydrogen induced stress cracking hisc. Critical hydrogen concentration for hydrogen induced cracking of type 321 stainless steel l. Critical hydrogen concentration for hydrogeninduced. Influence of hydrogen on corrosion and stress induced cracking of. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms.
For 308l and 347l weld metals of austenitic stainless steels ass, hydrogen induced cracking hic occurred during the dynamical charging under constant. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering due to hic. An illustration of cracking associated with the hydrogen embrittlement of austenitic stainless steel that is pulled in tension. Hydrogen induced cracking steel features, applications. In order to evaluate the resistance to hydrogeninduced cracking of pipeline and pressure vessel steel, standard test shall be conducted in accordance with nace tm0284. The significance of these failures has led to research to define critical loading conditions for hisc, to allow confident design of components in future. This article discusses hydrogen embrittlement of carbon steel. At hardness levels above 22 hrc, steel becomes less resistant to hydrogen induced cracking and other environmental effects.
They may also experience longterm failures anytime from weeks to decades after being placed in service due to accumulation of hydrogen over time from cathodic protection and other sources. Hydrogen induced stress cracking of swaged super duplex. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. When the two hydrogen atoms meet, they will combine to form molecular hydrogen which act like a gas and creates pressure within the steel. The 174 precipitation hardening ph stainless steel ss is being widely used in highpressure corrosive environments due to its high strength and e. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. A model has been developed which simulates the deformation of single crystal austenitic stainless steels and captures the effects of hydrogen on stress corrosion cracking. Modelling hydrogen induced stress corrosion cracking in. It is also explained that how to test the damage due to hydrogen embrittlement in stainless steel.
Hydrogen cracking in metastable austenitic stainless steels. Corrosionpedia what is hydrogeninduced cracking hic. Hydrogen evolution during activation of a duplex stainless steel specimen. Another type of hydrogen corrosion, stressorientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the vessel and the stress on the weld point itself. Hydrogen cracking in duplex stainless steel weld metal. Journal of iron and steel research international 22. Hydrogen cracking in stainless steel relationship between hydrogen induced martensite and hydrogen related fracture, a number of questions regarding the exact nature of the relationship remain unresolved despite the large amount of work in the area of hydrogen effects on. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Abstract the oil and gas industry has the last few years experienced several major failures in subsea components made of duplex stainless steel due to hydrogen induced stress cracking hisc with hydrogen introduced from the cathodic protection syst. Duplex stainless steels 86, the hague, the netherlands, 2628 october 1986, nederlands institut voor latechniek, 1986, paper 26, 268279. Hydrogen cracking of ferriticaustenitic stainless steel. The oil and gas industry has the last few years experienced several major failures in subsea components made of duplex stainless steel due to hydrogen induced stress cracking hisc with hydrogen introduced from the cathodic protection system.
Hydrogen induced cracking of subsea duplex stainless steel twi. The factors of hydrogen embrittlement and ways to prevent it is. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Susceptibility to embrittlement in hydrogen gas was investigated for three types of stainless steel alloys having different microstructures. The blistering damage tends to form parallel to the.
Hydrogen diffuses along the grain boundaries and combines with the carbon, which is alloyed with the iron, to form methane gas. Hydrogen embrittlement of 316l stainless steels exposed in. Naceastm g193 1 includes the following description of hydrogen blistering. Factors affecting inservice cracking of weld zone in. Experience has shown that stainless steels can suffer from hydrogen induced stress cracking hisc under cathodic protection in seawater. Johnsen, hydrogen induced stress cracking of duplex stainless steel in seawaterwhat do we know and what is still unknown. Additionally, hydrogen atoms diffuse through metals and coalesce. Critical hydrogen concentration for hydrogeninduced cracking of type 321 stainless steel l. Both slow strain rate notched tension tests and constant load crack propagation tests were used to evaluate susceptibility at 0 to 200c in hydrogen gas at 108 kpa 1 psig. Qiao 1 department of mechanical engineering, university of calgary, 2500 university dr.
May 19, 2009 susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. Hydrogen induced stress cracking of duplex stainless steel subsea components. Woollin p and murphy w, hydrogen embrittlement stress cracking of superduplex stainless steel, proc conf corrosion 2001, nace international, paper 01018. Another type of hydrogen corrosion, stressorientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the. Technical reference on hydrogen compatibility of materials. Hydrogen cracking in stainless steel relationship between hydrogeninduced martensite and hydrogenrelated fracture, a number of questions regarding the exact nature of the relationship remain unresolved despite the large amount of work in the area of hydrogen effects on. Incoloy 825 is superiorly immune to stainless steel grade 316 in the chloride media due to larger content of nickel. Hydrogen induced stress cracking hisc resistance and. Stress corrosion cracking behavior of nickel base alloys. Hydrogen induced cracking of subsea duplex stainless steel. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. The presence of hydrogen atoms in a metal degrades some of its mechanical properties, especially its ductility, leading in some cases to embrittlement. The blistering damage tends to form parallel to the surface and to the direction of hoop stress.
In addition, the higher concentration of hydrogen increases the chances of hydrogen embrittlement. This paper examines the factors determining weld metal hydrogen cracking. Wet hydrogen sulfide h2s cracking inspectioneering. At high hardness above about 40 hrc, steel becomes quite susceptible to cracking in the presence of hydrogen. Hydrogen induced cracking hic and the blistering of carbon steel are both such unexpected corrosion phenomenon. Hydrogen induced cracking hiccauses and prevention. Although it is known that there is a 2329 2330 rosenak and eliezer.
The steel specimens shall be immersed into test solutions at the temperature 253c 775f. Hydrogen enhances the mobility of dislocations and decreases the separation distance between dislocations in a pileup hydrogen restricts crossslip by stabilizing edge character dislocations. Generally, the tendency toward hydrogen cracking decreases with increasing temperature. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. In highstrength steels, anything above a hardness of hrc 32 may be susceptible to early hydrogen cracking after plating processes that introduce hydrogen. Low temperature has been shown to have a significant effect on the hydrogen assisted fracture of type 316 stainless steel.
This is a problem commonly found in wet h2ssour service operating environments such as in the oil, gas and petrochemical industry. Critical hydrogen concentration for hydrogeninduced cracking. Carbon seamless steel tube are mainly used for transporting high pressure oil and gas near the wellhead. The methane gas is not mobile and collects in small voids along the grain boundaries where it builds up enormous pressures that initiate cracks. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Combatting the problem of hydrogen induced cracking in sour service, hic steel plate is carbon steel plates which are tested to assess the susceptibility of the material to hydrogen induced cracking. It explains how hydrogen embrittlement occurs in stainless steel. Specimens of duplex stainless steel weld metal were prepared and slow strain rate tensile test was performed after hydrogen charging. The formation of subsurface planar cavities, called hydrogen blisters, in a metal. The programme sought to generate cracking data for sma welds, in 22%cr duplex stainless steel, for which the consumable hydrogen level had been determined using the vhe method. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Type 304 is a metastable austenite, and it is very susceptible to martensite formation. Hydrogen induced cracking hic when corrosion of steel occurs in an acid solution e.
Hydrogen induced cracking in austeniticferritic duplex stainless steels, proc conf. As the corrosion of hydrogen sulfide becomes more and more serious, the development of sulfurresistant seamless pipes is imminent, and the sulfur resistance is the key. Phase changes related to hydrogeninduced cracking in. Nov 28, 2018 hydrogen induced cracking, or hydrogen embrittlement, is a chemical phenomenon that causes metal alloys to fracture due to a buildup of hydrogen molecules within the crystal lattice structure. In potentially critical environments, the weld joint properties must be carefully controlled. Smooth bar tensile properties of 316 at several temperatures between. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Hydrogen induced cracking steel features, applications and. This type of austenitic stainless steels was used extensively in investigating hydrogen embrittlement behavior because of its material composition, structure instability, intergranular cracking mode, and ability to phase transform upon hydrogen charging or induced strain.
A few ppm of absorbed gas can be sufficient to induce cracks. Hydrogeninduced cracking of carbon seamless steel tube. It is clear that in both cases, cracking occurs at many locations. Hydrogen transport, microstructure, and hydrogen induced. The mode of hydrogen induced delayed fracture in either the stable or unstable austenitic stainless steel is correlated with thek, value. Jul 29, 2019 hydrogen induced cracking hic when corrosion of steel occurs in an acid solution e. This is a unique mode of mechanical failure that most commonly affects low alloys and highhardness steel grades such as titanium ti. Hydrogeninduced stress cracking of swaged super duplex. Hydrogeninduced cracking of weld metal of austenitic. In this study, the influence of the microstructure on hydrogen induced cracking behavior of duplex stainless steel weld metal was investigated.
Pdf hydrogeninduced cracking of a stainlesssteel dryer support. Based upon the results obtained, it was recommended to use an alloy more resistant to hydrogeninduced cracking such as the 309type stainless steel. This includes a discussion of the mechanism by which a steel becomes embrittled by hydrgogen, circumstances that lead to embrittlement, the effects of embrittlement on steel behavior, how to prevent the embrittlement, and tests for evaluating whether a steel has been embrittled. Proceedings of the asme 2010 29th international conference on ocean, offshore and arctic engineering. Hydrogeninduced cracking an overview sciencedirect topics. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. In order for heat affected zone cracking to occur, three. Cracking occurred in welds containing 83% ferrite and hydrogen levels of 11. Effect of plastic deformation on hydrogen induced cracking. Hydrogen embrittlement of 316l type austenitic stainless steel has been studied by charging thin tensile specimens 0. This article explains all about hydrogen embrittlment in stainless steel. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms.
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